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Clay and Magnetic Sand Biomass Based Composite for Methylene Blue Adsorption (Effects of Composition Ratios of Functional Materials and Synthesis Conditions)

Received: 28 October 2021     Accepted: 17 November 2021     Published: 25 November 2021
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Abstract

In recent times, iron oxide based magnetic nanoparticles (mainly magnetite (Fe3O4) or maghemite (γ-Fe2O3)) as well as clay and clay based composites, have become very important in the elimination of persistent organic compounds from waste water systems. This has been carried out by magnetic assisted chemical separation (MACS) process. The feasibility of using two locally sourced materials: magnetic black sand from down beach Limbe and clay from Bamessing Ndop for the removal of methylene blue (MB) dye from aqueous solution have been studied. The effects of contact time, pH, adsorbent dosage, temperature, grinding / length of grinding, composition ratios of the functional materials such as peel, pectin and starch, hydrothermal carbonization and concentration of dye solution were investigated. The test samples have exhibited great potentials for use in waste water purification for the removal of persistent organic compounds such as methylene blue dye. The results revealed that, varying various compositional ratios of the functional materials such as peel, pectin and starch to increase their affinity, selectivity, or degradation capacity towards targeted compounds influenced the activities of the adsorbents. The results also indicated that maximum performance was reached at pH value of 8 for Iron oxide (sand) based adsorbents and 12 for clay based adsorbents. Grinding / increase in grinding time have shown positive effects on the adsorbent properties of the composite from black sand and maximum grinding time varied depending on the compositional ratios of functional materials. Also within a certain threshold, hydrothermal carbonization improved on the adsorbent efficiency of the samples formulated with saccharides. The adsorption kinetic of methylene blue onto the adsorbents could be better fitted by the linear Langmuir isotherm and the pseudo-second-order model was a better model fitting the kinetics of the adsorption in this study.

Published in American Journal of Nanosciences (Volume 7, Issue 4)
DOI 10.11648/j.ajn.20210704.13
Page(s) 82-95
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2021. Published by Science Publishing Group

Keywords

Methylene Blue, Magnetic Sand, Iron Oxide, Clay, Hydrothermal Carbonization

References
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    Mih Venasius Nsom, Ekane Peter Etape, Beckley Victorine Namondo, Josepha Foba-Tendo, Lena Yoh Elango Ekaney. (2021). Clay and Magnetic Sand Biomass Based Composite for Methylene Blue Adsorption (Effects of Composition Ratios of Functional Materials and Synthesis Conditions). American Journal of Nanosciences, 7(4), 82-95. https://doi.org/10.11648/j.ajn.20210704.13

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    ACS Style

    Mih Venasius Nsom; Ekane Peter Etape; Beckley Victorine Namondo; Josepha Foba-Tendo; Lena Yoh Elango Ekaney. Clay and Magnetic Sand Biomass Based Composite for Methylene Blue Adsorption (Effects of Composition Ratios of Functional Materials and Synthesis Conditions). Am. J. Nanosci. 2021, 7(4), 82-95. doi: 10.11648/j.ajn.20210704.13

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    AMA Style

    Mih Venasius Nsom, Ekane Peter Etape, Beckley Victorine Namondo, Josepha Foba-Tendo, Lena Yoh Elango Ekaney. Clay and Magnetic Sand Biomass Based Composite for Methylene Blue Adsorption (Effects of Composition Ratios of Functional Materials and Synthesis Conditions). Am J Nanosci. 2021;7(4):82-95. doi: 10.11648/j.ajn.20210704.13

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  • @article{10.11648/j.ajn.20210704.13,
      author = {Mih Venasius Nsom and Ekane Peter Etape and Beckley Victorine Namondo and Josepha Foba-Tendo and Lena Yoh Elango Ekaney},
      title = {Clay and Magnetic Sand Biomass Based Composite for Methylene Blue Adsorption (Effects of Composition Ratios of Functional Materials and Synthesis Conditions)},
      journal = {American Journal of Nanosciences},
      volume = {7},
      number = {4},
      pages = {82-95},
      doi = {10.11648/j.ajn.20210704.13},
      url = {https://doi.org/10.11648/j.ajn.20210704.13},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajn.20210704.13},
      abstract = {In recent times, iron oxide based magnetic nanoparticles (mainly magnetite (Fe3O4) or maghemite (γ-Fe2O3)) as well as clay and clay based composites, have become very important in the elimination of persistent organic compounds from waste water systems. This has been carried out by magnetic assisted chemical separation (MACS) process. The feasibility of using two locally sourced materials: magnetic black sand from down beach Limbe and clay from Bamessing Ndop for the removal of methylene blue (MB) dye from aqueous solution have been studied. The effects of contact time, pH, adsorbent dosage, temperature, grinding / length of grinding, composition ratios of the functional materials such as peel, pectin and starch, hydrothermal carbonization and concentration of dye solution were investigated. The test samples have exhibited great potentials for use in waste water purification for the removal of persistent organic compounds such as methylene blue dye. The results revealed that, varying various compositional ratios of the functional materials such as peel, pectin and starch to increase their affinity, selectivity, or degradation capacity towards targeted compounds influenced the activities of the adsorbents. The results also indicated that maximum performance was reached at pH value of 8 for Iron oxide (sand) based adsorbents and 12 for clay based adsorbents. Grinding / increase in grinding time have shown positive effects on the adsorbent properties of the composite from black sand and maximum grinding time varied depending on the compositional ratios of functional materials. Also within a certain threshold, hydrothermal carbonization improved on the adsorbent efficiency of the samples formulated with saccharides. The adsorption kinetic of methylene blue onto the adsorbents could be better fitted by the linear Langmuir isotherm and the pseudo-second-order model was a better model fitting the kinetics of the adsorption in this study.},
     year = {2021}
    }
    

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  • TY  - JOUR
    T1  - Clay and Magnetic Sand Biomass Based Composite for Methylene Blue Adsorption (Effects of Composition Ratios of Functional Materials and Synthesis Conditions)
    AU  - Mih Venasius Nsom
    AU  - Ekane Peter Etape
    AU  - Beckley Victorine Namondo
    AU  - Josepha Foba-Tendo
    AU  - Lena Yoh Elango Ekaney
    Y1  - 2021/11/25
    PY  - 2021
    N1  - https://doi.org/10.11648/j.ajn.20210704.13
    DO  - 10.11648/j.ajn.20210704.13
    T2  - American Journal of Nanosciences
    JF  - American Journal of Nanosciences
    JO  - American Journal of Nanosciences
    SP  - 82
    EP  - 95
    PB  - Science Publishing Group
    SN  - 2575-4858
    UR  - https://doi.org/10.11648/j.ajn.20210704.13
    AB  - In recent times, iron oxide based magnetic nanoparticles (mainly magnetite (Fe3O4) or maghemite (γ-Fe2O3)) as well as clay and clay based composites, have become very important in the elimination of persistent organic compounds from waste water systems. This has been carried out by magnetic assisted chemical separation (MACS) process. The feasibility of using two locally sourced materials: magnetic black sand from down beach Limbe and clay from Bamessing Ndop for the removal of methylene blue (MB) dye from aqueous solution have been studied. The effects of contact time, pH, adsorbent dosage, temperature, grinding / length of grinding, composition ratios of the functional materials such as peel, pectin and starch, hydrothermal carbonization and concentration of dye solution were investigated. The test samples have exhibited great potentials for use in waste water purification for the removal of persistent organic compounds such as methylene blue dye. The results revealed that, varying various compositional ratios of the functional materials such as peel, pectin and starch to increase their affinity, selectivity, or degradation capacity towards targeted compounds influenced the activities of the adsorbents. The results also indicated that maximum performance was reached at pH value of 8 for Iron oxide (sand) based adsorbents and 12 for clay based adsorbents. Grinding / increase in grinding time have shown positive effects on the adsorbent properties of the composite from black sand and maximum grinding time varied depending on the compositional ratios of functional materials. Also within a certain threshold, hydrothermal carbonization improved on the adsorbent efficiency of the samples formulated with saccharides. The adsorption kinetic of methylene blue onto the adsorbents could be better fitted by the linear Langmuir isotherm and the pseudo-second-order model was a better model fitting the kinetics of the adsorption in this study.
    VL  - 7
    IS  - 4
    ER  - 

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Author Information
  • Department of Chemistry, Faculty of Science, University of Buea, Buea, Cameroon

  • Department of Chemistry, Faculty of Science, University of Buea, Buea, Cameroon

  • Department of Chemistry, Faculty of Science, University of Buea, Buea, Cameroon

  • Department of Chemistry, Faculty of Science, University of Buea, Buea, Cameroon

  • Department of Chemistry, Faculty of Science, University of Buea, Buea, Cameroon

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